Chemoenzymatic synthesis of homochiral (R)- and (S)-karahanaenol from (R)-limonene.
IR@CFTRI: CSIR-Central Food Technological Research Institute, Mysore
View Archive Info| Field | Value | |
| Relation |
http://ir.cftri.com/2178/
JOAFC-24-99 |
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| Title |
Chemoenzymatic synthesis of homochiral (R)- and (S)-karahanaenol from (R)-limonene.
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| Creator |
Roy, A
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| Subject |
12 Aromatic Chemistry
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| Description |
Terpinolene oxide, a monoterpene belonging to the p-menthane group, is easily derived from naturally abundant (R)-limonene. It was isomerized with montmorillonite clay catalyst to karahanaenone (2,2, 5-trimethylcyclohept-4-en-1-one) by ring enlargement. The enantiomers of the corresponding alcohol, karahanaenol (2,2, 5-trimethylcyclohept-4-en-1- ol), known for their individual organoleptic properties, were resolved through Pseudomonas cepacia lipase mediated enantiospecific alcoholysis of its acetate derivative.
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| Date |
1999
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Language |
en
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| Rights |
—
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| Identifier |
http://ir.cftri.com/2178/1/J._Agric._Food_Chem._1999%2C_47%2C_5209-5210.pdf
Roy, A (1999) Chemoenzymatic synthesis of homochiral (R)- and (S)-karahanaenol from (R)-limonene. Journal of agricultural and food chemistry, 47 (12). pp. 5209-5210. ISSN 0021-8561 |
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