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Y2O2S : Eu31 nanocrystals—synthesis and luminescent properties

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Y2O2S : Eu31 nanocrystals—synthesis and luminescent properties
 
Creator Dhanaraj, J.
Jagannathan, R.
Trivedi, D.C.
 
Subject Electrochemical Materials Science
 
Description Luminescent Y2O2S : Eu31 nanoceramics having an average particle size of 20 nm has been prepared through a gel–polymer thermolysis process employing a urea–formaldehyde resin. In this nanocrystalline system, large blue shifts (in relation to the bulk system) of y5000 cm21 and y2000 cm21 in the photoluminescence excitation bands corresponding to the excitonic region and the Eu31–ligand charge transfer region respectively have been observed. These may be explained by considering possible size dependent changes in optical electronegativity and quantum confinement effects occurring in this large bandgap semiconductor system.
 
Publisher The Royal Society of Chemistry
 
Date 2003
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/880/1/39-2003.pdf
Dhanaraj, J. and Jagannathan, R. and Trivedi, D.C. (2003) Y2O2S : Eu31 nanocrystals—synthesis and luminescent properties. Journal of Materials Chemistry, 13. pp. 1778-1782. ISSN 0959-9428
 
Relation http://cecri.csircentral.net/880/