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Conversion reactions: a new pathway to realise energy in lithium-ion battery—review

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Conversion reactions: a new pathway to realise energy in lithium-ion battery—review
 
Creator Malini, R.
Uma, U.
Sheela, T.
Ganesan, M.
Renganathan, N.G.
 
Subject Lithium batteries
 
Description Rechargeable lithium-ion batteries of today operate by an electrochemical process that involves intercalation reactions that warrants the use of electrode materials having very specific structures and properties. Further, they are limited to the insertion of one Li per 3D metal. One way to circumvent this intrinsic limitation and achieve higher capacities would be the use of electrode materials in which the metal-redox oxidation state could reversibly change by more than one unit. Through the discovery of conversion or displacement reactions, it is possible to reversibly change by more than one unit. Further, the need for materials with open structures or good electronic ionic conductivity is eliminated, thus leading to a new area in materials for lithium ion battery. In this paper, we present a review enlightens new reaction schemes and their potential impact on applications.
 
Publisher Springer-Verlag
 
Date 2008
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/374/1/064-2009.pdf
Malini, R. and Uma, U. and Sheela, T. and Ganesan, M. and Renganathan, N.G. (2008) Conversion reactions: a new pathway to realise energy in lithium-ion battery—review. Ionics, 15 (3). pp. 301-307. ISSN 0947-7047
 
Relation http://cecri.csircentral.net/374/