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Process Parameters and Kinetics for the Electrochemical Generation of Cerium(IV) Methanesulphonate from Cerium(III) Methanesulphonate

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Process Parameters and Kinetics for the Electrochemical Generation of Cerium(IV) Methanesulphonate from Cerium(III) Methanesulphonate
 
Creator Raju, T.
Basha, C.A.
 
Subject Electroorganic
Pollution Control
 
Description To study and optimize the process parameters such as current density, temperature, concentration of cerium(III) methanesulphonate and methanesulphonic acid, and kinetics for the electrochemical generation of cerium(IV) methanesulphonate in aqueous methane sulfonic acid medium. A 97% current efficiency and conversion was achieved at 5 A/dm2 current density in 0.8 M cerium(III) methanesulphonate with 2 M methanesulphonic acid medium at 50 °C temperature.
 
Publisher American Chemical Society
 
Date 2008
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/117/1/046-2008.pdf
Raju, T. and Basha, C.A. (2008) Process Parameters and Kinetics for the Electrochemical Generation of Cerium(IV) Methanesulphonate from Cerium(III) Methanesulphonate. Industrial and Engineering Chemistry Research, 47 (22). pp. 8947-8952. ISSN 0888-5885
 
Relation http://cecri.csircentral.net/117/