Electron transfer studies through mixed self-assembled monolayers of thiophenol and thioctic acid
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
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Title |
Electron transfer studies through mixed self-assembled monolayers of thiophenol and thioctic acid
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Creator |
Ramalechume, C.
Sheela, B. Yegnaraman, V. Mandal, A.B. |
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Subject |
Electrodics and Electrocatalysis
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Description |
Mixed self-assembled monolayer of thiols were formed on the electrode surface using aromatic and aliphatic thiols and the modified
interface were used to demonstrate charge trapping behavior at the modified interface. The electrode surface was modified by
two schemes. In Scheme 1, electrode surface modified with methylene blue (MB) shows charge trapping behavior when contacts the
electrolyte containing potassium ferricyanide. In Scheme 2, a redox-active bilayer is constructed using hexamineruthenium (II) chloride
and methylene blue. This redox-active bilayer assembly exhibits unidirectional flow of current.
� 2005 Elsevier B.V. All rights reserved.
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Publisher |
Elsevier
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Date |
2005
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://cecri.csircentral.net/98/1/048-2005.pdf
Ramalechume, C. and Sheela, B. and Yegnaraman, V. and Mandal, A.B. (2005) Electron transfer studies through mixed self-assembled monolayers of thiophenol and thioctic acid. Journal of Electroanalytical Chemistry, 580 (1). pp. 122-127. |
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Relation |
http://cecri.csircentral.net/98/
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