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Characterization of poly(vinylidene fluoride–hexafluoropropylene) (PVdF–HFP) electrolytes complexed with different lithium salts

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Characterization of poly(vinylidene fluoride–hexafluoropropylene) (PVdF–HFP) electrolytes complexed with different lithium salts
 
Creator Stephan, A.M.
Gopukumar, S.
Renganathan, N.G.
Anbukulandainathan, M.
 
Subject Lithium batteries
 
Description Poly(vinylidene fluoride–hexafluoropropylene) (PVdF–HFP) gel electrolytes comprising a combination of plasticizers, ethylene carbonate (EC) and propylene carbonate (PC) and lithium salt LiX ðX ¼ BF�4 ;CF3SO�3 ; ClO�4 Þ have been prepared using the solution casting technique in an argon atmosphere. The prepared electrolytes were subjected to ionic conductivity, compatibility with lithium metal anode and thermogravimetric (TG)/differential thermal analysis (DTA). The membranes, which possess lithium salt, LiBF4 exhibited maximum conductivity and on contrary it undergoes severe passivation with lithium metal. All these membranes are found to be stable thermally about 70�C.
 
Publisher Elsevier
 
Date 2005
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/62/1/028-2005.pdf
Stephan, A.M. and Gopukumar, S. and Renganathan, N.G. and Anbukulandainathan, M. (2005) Characterization of poly(vinylidene fluoride–hexafluoropropylene) (PVdF–HFP) electrolytes complexed with different lithium salts. European Polymer Journal, 41 (1). pp. 15-21.
 
Relation http://cecri.csircentral.net/62/