Tandem Catalysis by Lipase in a Vinyl Acetate-Mediated Cross-Aldol Reaction
IR@IIIM: CSIR-Indian Institute of Integrative Medicine, Jammu
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| Title |
Tandem Catalysis by Lipase in a Vinyl Acetate-Mediated Cross-Aldol Reaction
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| Creator |
Kumar, Manjeet
Shah, Bhahwal A. Taneja, Subhash C. |
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| Subject |
Chemical Sciences
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| Description |
The lipase Novozym435 (0.6% w/w) was used in tandem with organocatalysts in a first vinyl/isopropenyl acetate-mediated aldol reaction. The reaction was facilitated through the lipase-catalyzed in situ generation of acetaldehyde/acetone. The importantfeatures of the present methodology include the mild and facile reaction conditions, regenerability of the lipase, comparatively high yields and minimal side product formation.
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| Date |
2011
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://iiim.csircentral.net/359/1/10.1002adsc.201000980.pdf
Kumar, Manjeet and Shah, Bhahwal A. and Taneja, Subhash C. (2011) Tandem Catalysis by Lipase in a Vinyl Acetate-Mediated Cross-Aldol Reaction. Advanced Synthesis & Catalysis, 353 (8). pp. 1207-1212. ISSN 16154150 |
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| Relation |
http://dx.doi.org/10.1002/adsc.201000980
http://iiim.csircentral.net/359/ |
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