Density, ultrasonic velocity, electrical conductivity, viscisity and Raman Spectra of methanolic Mg(ClO4)2, Mg(NO3)2 and Mg(OAc)2 solutions
IR@NEIST: CSIR-North East Institute of Science and Technology, Jorhat
View Archive Info| Field | Value | |
| Title |
Density, ultrasonic velocity, electrical conductivity, viscisity and Raman Spectra of methanolic Mg(ClO4)2, Mg(NO3)2 and Mg(OAc)2 solutions
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| Creator |
Wahab , A
Mahiuddin , S |
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| Subject |
Material Science
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| Description |
Density, ultrasonic velocity, electrical conductivity, viscosity, and Raman spectra of methanolic Mg(ClO4)2,
Mg(NO3)2, and Mg(OAc)2 solutions were measured as functions of concentration (dilute to saturation) and
temperature (273.15 e T/K e 313.15). The isentropic compressibility, electrical conductivity, and Raman
spectral data reveal the following order of anion-solvent interactions and mobility in methanol: OAc- <
NO3
- < ClO4
-. Anionic effect on the isentropic compressibility and conductivity roughly appear to follow
Hofmeister series. Transport properties and Raman spectra also indicate a moderate solvent-shared ion pairing
in concentrated Mg(NO3)2 solutions.
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| Publisher |
ACS
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| Date |
2009
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://neist.csircentral.net/47/1/2594_J_chem_engg_data2009.pdf
Wahab , A and Mahiuddin , S (2009) Density, ultrasonic velocity, electrical conductivity, viscisity and Raman Spectra of methanolic Mg(ClO4)2, Mg(NO3)2 and Mg(OAc)2 solutions. J Chemical Engineering Data, 54 (2). pp. 436-443. |
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| Relation |
http://neist.csircentral.net/47/
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