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Water-promoted cascade synthesis of a-arylaldehydes from arylalkenes using N-halosuccinimides: an avenue for asymmetric oxidation using Cinchona organocatalysis.

IR@IHBT: CSIR-Institute of Himalayan Bioresource Technology, Palampur

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Title Water-promoted cascade synthesis of a-arylaldehydes from arylalkenes using N-halosuccinimides: an avenue for asymmetric oxidation using Cinchona organocatalysis.
 
Creator Sharma, A
Sharma, N
Kumar, R
Sharma, U K
Sinha, Arun K
 
Subject Chemical Engineering
 
Description The direct oxidation of arylalkenes into a-arylaldehydes is achieved for the first time in water without relying on transition metal catalysts, and a novel organocatalytic enantioselectiveapproach is also explored to provide up to 30% ee in initial investigations.
 
Publisher Royal Society of Chemistry , Thomas Graham House, Science Park, Milton Rd, Cambridge CB4 0WF, Cambs, England .
 
Date 2009
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://ihbt.csircentral.net/137/1/2009_Water%2Dpromoted.pdf
Sharma, A and Sharma, N and Kumar, R and Sharma, U K and Sinha, Arun K (2009) Water-promoted cascade synthesis of a-arylaldehydes from arylalkenes using N-halosuccinimides: an avenue for asymmetric oxidation using Cinchona organocatalysis. Chemical Communication, 35. pp. 5299-5301. ISSN 1359-7345
 
Relation http://ihbt.csircentral.net/137/