Stereoselective synthesis of homoallyl nitroalkane derivatives via base-promoted regioselective decarboxylation in Baylis-Hillman derivatives
IR@CDRI: CSIR-Central Drug Research Institute, Lucknow
View Archive InfoField | Value | |
Creator |
Nayak, Maloy
Batra, Sanjay |
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Date |
2010-03-04T06:15:42Z
2010-03-04T06:15:42Z 2009 |
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Identifier |
Eur. J. Org. Chem. 2009, 3505–3507
http://hdl.handle.net/123456789/525 |
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Description |
The regioselective decarboxylation during the saponification of the nitroalkanoates synthesized from the Baylis-Hillman acetates of acrylates to stereoselectively afford homoallyl nitroalkane is described. In contrast the similar nitroalkanoates derived from the Baylis-Hillman acetates of acrylonitrile gave bis allyl nitroalkanes.
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Format |
108505 bytes
application/pdf |
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Language |
en
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Relation |
CDRI Communication Number 7756
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Subject |
Homoallyl nitroalkane
regioselective Baylis-Hillman decarboxylation bis-allylnitroalkane |
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Title |
Stereoselective synthesis of homoallyl nitroalkane derivatives via base-promoted regioselective decarboxylation in Baylis-Hillman derivatives
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Type |
Article
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