Ti(III)-Mediated Radical Cyclization of β-Aminoacrylate Containing Epoxy Alcohol Moieties: Synthesis of Highly Substituted Azacycles
IR@CDRI: CSIR-Central Drug Research Institute, Lucknow
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Creator |
Chakraborty, Tushar Kanti
Samanta, Rajarshi Roy, Saumya Balasubramanian, Sridhar |
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Date |
2009-05-20T15:00:11Z
2009-05-20T15:00:11Z 2009 |
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Identifier |
Tetrahedron Letters,50,3306–3310 (2009)
http://hdl.handle.net/123456789/442 |
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Description |
Ti(III)-mediated radical cyclization of β-aminoacrylate containing 2,3-epoxy alcohol moieties led to the formation of highly substituted piperidine and pyrrolidine rings. The pyrrolidine ring system was then transformed into an indolizidine framework present in many natural products.
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Format |
273805 bytes
application/pdf |
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Language |
en
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Relation |
CDRI Communication No.7694
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Subject |
Piperidine
pyrrolidine indolizidine Ti(III)-mediated epoxide opening radical cyclization β-aminoacrylates |
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Title |
Ti(III)-Mediated Radical Cyclization of β-Aminoacrylate Containing Epoxy Alcohol Moieties: Synthesis of Highly Substituted Azacycles
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Type |
Article
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