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Significant yield improvement in the stereoselective synthesis of allyl cyanides from Baylis-Hillman derivatives in aqueous medium under the influence of the Phase-Transfer catalyst

IR@CDRI: CSIR-Central Drug Research Institute, Lucknow

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Field Value
 
Creator Singh, Vijay
Pathak, Richa
Batra, Sanjay
 
Date 2007-12-29T08:17:05Z
2007-12-29T08:17:05Z
2007
 
Identifier Catalysis Communications (2007), 8, 2048-2052
http://hdl.handle.net/123456789/72
 
Description The nucleophilic reaction of NaCN with the acetyl derivative of Baylis-Hillman adducts in the presence of a phase-transfer catalyst in aqueous medium stereoselectively affords the corresponding allyl cyanides in a short period and excellent yields.
 
Format 101405 bytes
application/pdf
 
Language en
 
Relation CDRI Communication no. 7169
 
Subject Baylis-Hillman
allyl cyanide
NaCN
phase-transfer catalyst
water
 
Title Significant yield improvement in the stereoselective synthesis of allyl cyanides from Baylis-Hillman derivatives in aqueous medium under the influence of the Phase-Transfer catalyst
 
Type Article