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Single-walled carbon nanotube synthesis using Pt catalysts under low ethanol pressure via cold-wall chemical vapor deposition in high vacuum

IR@CMERI: CSIR- Central Mechanical Engineering Research Institute (CMERI), Durgapur

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Title Single-walled carbon nanotube synthesis using Pt catalysts under low ethanol pressure via cold-wall chemical vapor deposition in high vacuum
 
Creator Maruyama, Takahiro
Kondo, Hiroki
Ghosh, Ranajit
Kozawa, Akinari
Naritsuka, Shigeya
Iizumi, Yoko
Okazaki, Toshiya
Iijima, Sumio
 
Subject Materials
 
Description We study single-walled carbon nanotube (SWCNT) growth from Pt catalysts by a cold-wall chemical vapor deposition (CVD) method in a high vacuum using a nozzle injector for the ethanol gas supply. By optimizing the ethanol pressure, we could grow SWCNTs between 330 and 700 °C, and the optimal ethanol pressure to obtain the highest SWCNT yield was reduced as the growth temperature decreased. Using transmission electron microscopy, Raman spectroscopy and photoluminescence measurements, we determined the diameters and chirality distribution of the SWCNTs and showed that the grown SWCNTs have a narrow chirality distribution and that the diameters of most SWCNTs were below 1.0 nm. In addition, based on the size distribution and the chemical states of Pt catalyst particles, we proposed a growth model of the SWCNTs.
 
Publisher Elsevier
 
Date 2016-01
 
Type Article
PeerReviewed
 
Identifier Maruyama, Takahiro and Kondo, Hiroki and Ghosh, Ranajit and Kozawa, Akinari and Naritsuka, Shigeya and Iizumi, Yoko and Okazaki, Toshiya and Iijima, Sumio (2016) Single-walled carbon nanotube synthesis using Pt catalysts under low ethanol pressure via cold-wall chemical vapor deposition in high vacuum. Carbon, 96. pp. 6-13.
 
Relation http://cmeri.csircentral.net/420/