RuIII(edta) catalyzed hydrogenation of bicarbonate to formate
IR@CMERI: CSIR- Central Mechanical Engineering Research Institute (CMERI), Durgapur
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| Title |
RuIII(edta) catalyzed hydrogenation of bicarbonate to formate
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| Creator |
Chatterjee, Debabrata
Sarkar, Papiya |
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| Subject |
Chemistry
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| Description |
Selective hydrogenation of bicarbonate to formate catalyzed by a ruthenium(III) complex, [RuIII(edta)] (edta4− = ethylenediaminetetraacetate), at moderate H2 pressure (2–8 atm) and temperature (30–40 °C) is reported. Formation of formate, the only reduction product, was identified by 13C NMR analysis of the resultant reaction mixture. Based on the spectral data, a working mechanism (admittedly speculative) involving the formation of ruthenium(III)-bicarbonate complex, [RuIII(edta)(HCO3)]2−, is proposed for the catalytic reaction.
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| Publisher |
Taylor & Francis
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| Date |
2016
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| Type |
Article
PeerReviewed |
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| Identifier |
Chatterjee, Debabrata and Sarkar, Papiya (2016) RuIII(edta) catalyzed hydrogenation of bicarbonate to formate. Journal of Coordination Chemistry , 69 (4). pp. 650-655.
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| Relation |
http://cmeri.csircentral.net/415/
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