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Catalytic dehydrogenation of cyclohexane over Ag-M/ACC catalysts for hydrogen supply

IR@NEERI: National Environment Engineering Research Institute

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Field Value
 
Title Catalytic dehydrogenation of cyclohexane over Ag-M/ACC catalysts for hydrogen supply
 
Creator Pande, Jayshree V
Shukla, Anshu
Biniwale , Rajesh B.
 
Subject Materials Science
 
Description Dehydrogenation of cyclohexane to benzene has been carried out over Ag supported on activated carbon cloth (Ag/ACC) catalysts using a spray- pulse reactor. Hydrogen evolution was studied for hydrogen storage and supply system applications. The maximum rate of hydrogen evolution rate using monometallic Ag/ACC catalysts was 6.9 mmol/gmet/min for Ag loading of 10 wt%. An enhanced hydrogen evolution was observed by adding a small amount of noble metal (1 wt% Pt, Pd, Rh) to the Ag based catalysts. A synergistic effect was observed in the case of the Pt promoted catalysts on the hydrogen production were twice as compared to 10 wt% Ag catalyst only.
 
Publisher Elsevier
 
Date 2012-04
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://neeri.csircentral.net/528/1/Int_J_Hydrogen_Eng_37_2012_LOH_Ag-M.pdf
Pande, Jayshree V and Shukla, Anshu and Biniwale , Rajesh B. (2012) Catalytic dehydrogenation of cyclohexane over Ag-M/ACC catalysts for hydrogen supply. International Journal of Hydrogen Energy, 37 (8). pp. 6756-6763. ISSN 0360-3199
 
Relation http://www.sciencedirect.com/science/article/pii/S036031991200119X
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