Nitrite reduction mediated by the complex RuIII(EDTA)
IR@CMERI: CSIR- Central Mechanical Engineering Research Institute (CMERI), Durgapur
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| Title |
Nitrite reduction mediated by the complex RuIII(EDTA)
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| Creator |
Chatterjee, Debabrata
Shome, Sanchari Jaiswal, Namita Banerjee, Priyabrata |
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| Subject |
Chemistry
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| Description |
Reported is the first example of a ruthenium(III)-complex, RuIII(EDTA) (EDTA4− = ethylenediaminetetraacetate), that mediates O-atom transfer from nitrite to the biological thiols cysteine and glutathione, leading to the formation of [RuIII(EDTA)(NO+)]0. However, at pH below 5.0, the coordinated nitrite ion in the [RuIII(EDTA)(NO2)]2− complex undergoes proton-assisted decomposition, resulting in the formation of a [RuIII(EDTA)(NO+)]0 species.
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| Publisher |
Royal Society of Chemistry
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| Date |
2014
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| Type |
Article
PeerReviewed |
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| Identifier |
Chatterjee, Debabrata and Shome, Sanchari and Jaiswal, Namita and Banerjee, Priyabrata (2014) Nitrite reduction mediated by the complex RuIII(EDTA). Dalton Transactions, 43 (36). pp. 13596-13600.
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| Relation |
http://cmeri.csircentral.net/333/
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