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UPGRADATION OF SULFOLANE PROCESS USING COSOLVENTS

IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun

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Field Value
 
Creator Nautiyal,B.R
Khanna,M.K
Nanoti,S.M
Prasad,Guru
Paul,Dharam
Rawat,B.S
Garg,M.O
 
Date 2010-05-17T06:48:44Z
2010-05-17T06:48:44Z
2010-05-17T06:48:44Z
 
Identifier Proceedings of PETROTECH-2003,January 9-12, 2003, New Delhi
http://hdl.handle.net/123456789/569
 
Description Pure aromatics like Benzene, Toluene and Xylenes are primary feed stocks for the petrochemical industry. With the growing demand for petrochemicals more and more extraction capacity will be needed. Commercial extraction units for the production of pure aromatics, worldover use Sulfolane (more than 160 units) as solvent, followed by tetra ethylene glycol (more than 40 units). These solvents have high selectivity and optimum capacity. To enhance the capacity of these existing units, co-solvent have been tried which enhance the capacity of existing solvents. For example, CAROM process by UOP uses tetra ethylene glycol + some glycol ethers as cosolvents. The same can be considered to enhance the capacity of sulfolane units. In this study, attempts have been made for the detailed studies on extraction of aromatics from naphtha reformate (60-90°C) fraction and model hydrocarbons (representing naphtha reformate fraction) as feedstocks with sulfolane+ co-solvents under varying operating conditions followed by the solvent recovery step, with varying operating parameters i.e. cosolvent content of sulfolane, solvent to feed ratio, extraction temperature, etc. The results obtained in continuous extraction runs showed that S/F ratios of 2 to 3 is sufficient for extraction of aromatics in optimum yield and purity as compared to S/F ratio 4-6, in case of Sulpholane process.
 
Language en_US
 
Subject Co-Solvent
Extraction
Sulpholane
Selectivity
Capacity
Extract Yield
Extract Purity
 
Title UPGRADATION OF SULFOLANE PROCESS USING COSOLVENTS
 
Type Article