CSIR Central

Metallophthalocyanines (MPcs) as efficient heterogeneous catalysts for Biginelli condensation: Application and comparison in catalytic activity of different MPcs for one pot synthesis of 3,4-dihydropyrimidin-2-(1H)-ones

IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun

View Archive Info
 
 
Field Value
 
Creator Jain, Suman L
Joseph,Jomy K
Singhal,Sweety
Sain,Bir
 
Date 2009-06-19T10:52:09Z
2009-06-19T10:52:09Z
2009-06-19T10:52:09Z
 
Identifier http://hdl.handle.net/123456789/210
 
Description The catalytic efficiency of various metallophthalocyanineswas investigated for three-component condensation reaction of aldehyde, -dicarbonyl compound and urea to afford corresponding 3,4-dihydropyrimidinones. These phthalocyanine complexes were found to be efficient, recyclable heterogeneous catalyst and showed rate enhancements, high yields and short reaction times in this transformation. Among the various metallophthalocyanines studied, cobalt(II)- phthalocyanine was found to be most active for this transformation. Keywords: Biginelli reaction; Metallophthalocyanines; Heterogeneous catalysis; Dihydropyrimidinones
 
Language en_US
 
Subject Heterogeneous Catalysis
Dihydropyrimidinones
Metallophthalocyanines
Biginelli reaction
 
Title Metallophthalocyanines (MPcs) as efficient heterogeneous catalysts for Biginelli condensation: Application and comparison in catalytic activity of different MPcs for one pot synthesis of 3,4-dihydropyrimidin-2-(1H)-ones
 
Type Article