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Metallophthalocyanines as potent catalysts for aziridination of olefins

IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun

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Field Value
 
Creator Jain, Suman L
Sain, Bir
 
Date 2009-06-19T06:47:33Z
2009-06-19T06:47:33Z
2009-06-19T06:47:33Z
 
Identifier http://hdl.handle.net/123456789/196
 
Description Copper, manganese and iron phthalocyanines were found to be highly efficient catalysts for aziridination of olefins using [N-( p-tolylsulphonyl) imino] phenyliodinane, Chloramine-T and Bromamine-T as nitrene precursors. [N-( p-Tolylsulphonyl) imino] phenyliodinane was found to be better nitrene donor as compared to the Chloramine-T and Bromamine-T and aromatic substituted olefins were found to be more reactive as compared to the aliphatic alkenes under these conditions. © 2002 Elsevier Science B.V. All rights reserved. Keywords: Metallophthalocyanine; Nitrene, [N-( p-Tolylsulphonyl) imino] phenyliodinane; Chloramine-T; Bromamine-T
 
Language en_US
 
Subject Metallophthalocyanine
Phenyliodinane
Chloramine-T
Bromamine-T
Olefins
 
Title Metallophthalocyanines as potent catalysts for aziridination of olefins
 
Type Article