Metallophthalocyanines as potent catalysts for aziridination of olefins
IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun
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Creator |
Jain, Suman L
Sain, Bir |
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Date |
2009-06-19T06:47:33Z
2009-06-19T06:47:33Z 2009-06-19T06:47:33Z |
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Identifier |
http://hdl.handle.net/123456789/196
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Description |
Copper, manganese and iron phthalocyanines were found to be highly efficient catalysts for aziridination of olefins using
[N-( p-tolylsulphonyl) imino] phenyliodinane, Chloramine-T and Bromamine-T as nitrene precursors. [N-( p-Tolylsulphonyl)
imino] phenyliodinane was found to be better nitrene donor as compared to the Chloramine-T and Bromamine-T and aromatic
substituted olefins were found to be more reactive as compared to the aliphatic alkenes under these conditions.
© 2002 Elsevier Science B.V. All rights reserved.
Keywords: Metallophthalocyanine; Nitrene, [N-( p-Tolylsulphonyl) imino] phenyliodinane; Chloramine-T; Bromamine-T
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Language |
en_US
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Subject |
Metallophthalocyanine
Phenyliodinane Chloramine-T Bromamine-T Olefins |
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Title |
Metallophthalocyanines as potent catalysts for aziridination of olefins
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Type |
Article
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