Regioselective anodic α-methoxylation of 2-oxazolidinone on boron doped diamond in acidic methanol medium
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
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| Title |
Regioselective anodic α-methoxylation of 2-oxazolidinone on boron doped diamond in acidic methanol medium
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| Creator |
Saravanan, KR.
Selvamani, V. Kulangiappar, K. Velayutham, D. Suryanarayanan, V. |
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| Subject |
Electroorganic
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| Description |
For the first time, anodic methoxylation of 2-oxazolidinone was investigated on boron doped diamond (BDD)
in CH3OH\H2SO4 medium. Voltammetric studies reveal that the 2-oxazolidinone gets oxidised at a potential
of 1.5 V vs. SCE on the BDD, whereas on the graphite, the anodic oxidation takes place in the potential region
of methanol oxidation. Galvanostatic electrolysis results in the formation of 4-methoxy-2-oxazolidinone
(MOD) as a single product in high yield on the BDD and multiple products, along with MOD on the graphite.
Generation of methoxy radical on the BDD was confirmed by Electron Spin Resonance (ESR) spectroscopy.
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| Publisher |
Elsevier B.V
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| Date |
2013
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/3053/1/004-2013.pdf
Saravanan, KR. and Selvamani, V. and Kulangiappar, K. and Velayutham, D. and Suryanarayanan, V. (2013) Regioselective anodic α-methoxylation of 2-oxazolidinone on boron doped diamond in acidic methanol medium. Electrochemistry Communications, 28. pp. 31-33. ISSN 1388-2481 |
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| Relation |
http://www.elsevier.com/locate/elecom
http://cecri.csircentral.net/3053/ |
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