Solid supported palladium(0) nano/microparticle: a ligand-free efficient recyclable heterogeneous catalyst for mono- and b,b-double-Heck reaction
IR@IHBT: CSIR-Institute of Himalayan Bioresource Technology, Palampur
View Archive Info| Field | Value | |
| Title |
Solid supported palladium(0) nano/microparticle: a ligand-free efficient
recyclable heterogeneous catalyst for mono- and b,b-double-Heck reaction
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| Creator |
Sharma, Dharminder
Kumar, Sandeep Shil, Arun K Guha, Nitul Ranjan ------,, Bandna Das, Pralay |
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| Subject |
Natural Product Chemistry
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| Description |
Solid supported palladium nano/microparticles were found to be active catalysts to perform mono- and
b,b-double-Heck reactions. Different b-unsubstituted and substituted alkenes including acrylate, methacrylate,
crotonate, styrene, acrylonitrile, and acrylamide were investigated successfully for mono- and b,
b-double-Heck reactions with aryl iodide under milder reaction condition. One-pot b,b-double-Heck
reaction of aryl iodides with a,b-unsaturated ester, amide, nitrile, and styrene derivatives were also
performed under standard reaction conditions. Wide functional group tolerance, easy catalyst recovery,
and recyclability up to twelve times without significant loss of catalytic activity added extra importance
to the present process.
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| Date |
2012
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://ihbt.csircentral.net/1232/1/36_Solid_supported.pdf
Sharma, Dharminder and Kumar, Sandeep and Shil, Arun K and Guha, Nitul Ranjan and ------,, Bandna and Das, Pralay (2012) Solid supported palladium(0) nano/microparticle: a ligand-free efficient recyclable heterogeneous catalyst for mono- and b,b-double-Heck reaction. Tetrahedron Letters, 53. pp. 7044-7051. |
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| Relation |
http://ihbt.csircentral.net/1232/
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