Efficient hydrogen supply through catalytic dehydrogenation of methylcyclohexane over Pt/metal oxide catalysts
IR@IICT: CSIR-Indian Institute of Chemical Technology, Hyderabad
View Archive Info| Field | Value | |
| Creator |
Shukla Anshu, A
Priti, G.V Jayshri, V.P Kumar, V.P Chary, K.V.R Rajesh, B.B |
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| Date |
2012-07-04T05:04:43Z
2012-07-04T05:04:43Z 2010 |
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| Identifier |
International Journal of Hydrogen Energy, Vol.35(9), 4020-4026p
http://hdl.handle.net/123456789/7949 |
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| Description |
This paper describes the results of experiments on dehydrogenation of methylcyclohexane over Pt supported on metal oxides (Pt/MO) and Pt supported on perovskite (Pt/Per) catalysts. The reaction is being considered as a means for delivery of hydrogen to fueling stations in the form of more easily transportable methylcyclohexane. Among Pt/MO catalysts, the best
activity as determined by the hydrogen evolution rate was observed over Pt/La2O3 catalyst at 21.1 mmol/gmet/min. Perovskite-supported catalysts exhibited relatively higher activity and selectivity, with Pt/La0.7Y0.3NiO3 giving the best performance. This Pt/Per catalyst had
an activity of ca 45 mmol/gmet/min with nearly 100% selectivity towards dehydrogenation. The catalysts were characterized using XRD, CO-chemisorption and SEM-EDXA techniques. The present study reports catalysts that minimize the use of Pt and explores tailoring the properties of the perovskite structure.
IICT |
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| Language |
en
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| Publisher |
Elsevier
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| Subject |
Hydrogen delivery
Dehydrogenation Pt over metal oxide Perovskite Methylcyclohexane Pulse spray reactor |
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| Title |
Efficient hydrogen supply through catalytic dehydrogenation of methylcyclohexane over Pt/metal oxide catalysts
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| Type |
Article
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